Take a look at Ortho's "Brush-B-Gon". I've used it for years on poison ivy and it kills the entire plant. The spray can gives you enough range that you can get the hard to reach plants as well including the ones that have grown up trees. . A can costs a couple of bucks.

The stuff foams up where it hits so it's easy to target only the poison ivy and not kill other plants. I check out the new ivy locations as I work around the place each spring and take an hour or two later to spray them all. End of ivy.

Keep in mind the birds will distribute seeds again next year so chances are you'll still see more the next spring.

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